you need to check if you pc has real g-sync or its only g-sync compatible.
an example of true g-sync is the asus swift monitors,they have an integrated cpu (inside the monitor) that will handle the variable refresh rate with it and leave your gpu alone.
a g-sync compatible monitor will use the gpu (not the monitor cpu) to handle the variable refresh rates.
thats why a asus swift with g-sync costs 700 euro and a g-sync compatible monitor costs 150 euro.
g-sync compatible doesnt work good since its using the gpu to emulate what a tru g-sync monitor can do with its cpu without using your gpu to emulate it.
this is a bad from nvidia since many people buy g-sync compatible monitors thinking they will have g-sync and its not true g-sync,just your gpu being stressed with a emulation.
also bad from nvidia dont clarify this better!
freesync is same has g-sync compatible.
only true g-sync will work in wow since wow is borderless and only g-sync cpu chip (inside good monitors) can gsync in borderless.
i guess you bought a g-sync compatible instead of true g-sync.
PS: i just checked and you monitor is g-sync compatible not g-sync.
you got jebaited by nvidia+acer false advertising.
if i where you i refund the pc for false advertising (g-sync compatible is NOT g-sync) and buy a real g-sync.
you can tell its real g sync when the monitor itself has a gsync cpu inside of it.(thats why its way more expensive true g-sync.
you can also try enabling g-sync and v-sync in control pannel at same time,you will get a vsync game at you maximum refresh rate and gsync game when its below you max refresh rate,but will never behave has true g-sync only.